The Photos app is a Universal (Metro) app which comes pre-installed in Windows 10. This app is intended to replace Windows Photo Viewer, since Microsoft wants to make the whole user environment look and work the same on Windows 10 Mobile and Windows 10 for PCs. While interested users can restore the classic desktop app, Windows Photo Viewer, those who prefer to use Photos might be interested in learning its keyboard shortcuts.
Spacebar - While in the Collection mode, select an item and enter the Selection mode.
Enter - In the Selection mode allows you to select an item.
Spacebar - Show or hide commands while in photo viewing mode.
Play or pause the video in the video mode.
Arrow keys - Scroll up, down, left, or right in the Collection mode or Move within the photo on a zoomed photo
Left or Right arrow keys on a single item or slideshow - show the next or previous item
Ctrl++ - Zoom in when a photo opened in the app.
Ctrl+- - Zoom out when a photo opened in the app..
Ctrl+0 - Reset the image zoom.
Esc - Return to previous screen.
Ctrl+S - Save.
Ctrl+P - Print.
Ctrl+C - Copy.
Ctrl+R - Rotate a photo. Works in the view photo mode or when editing.
E - Enhance a photo while viewing.
Ctrl+Z - Undo changes in the editing mode.
Ctrl+Y - Redo changes in the editing mode.
Ctrl+/ - View original in the editing mode.
Shift+arrow keys - Resize crop or selective focus area.
Ctrl+arrow keys - Move crop or selective focus area.
F5 - Start a slide show.
Alt+Enter - View file info.
Ctrl+L - Set as lock screen.
Win+H - Open the Share charm.
That's it. If you know more hotkeys for the Photos app, feel free to share them in comments.
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